Greenhouse gases transformed into liquid fuel

Rice University researchers have found a common greenhouse gas could be repurposed in an efficient and environmentally friendly way with an electrolyzer that uses renewable electricity to produce pure liquid fuels.

By Mike Williams September 5, 2019

A common greenhouse gas could be repurposed in an efficient and environmentally friendly way with an electrolyzer that uses renewable electricity to produce pure liquid fuels. The catalytic reactor developed by the Rice University lab of chemical and biomolecular engineer Haotian Wang uses carbon dioxide as its feedstock and, in its latest prototype, produces highly purified and high concentrations of formic acid. Formic acid produced by traditional carbon dioxide devices needs costly and energy-intensive purification steps, Wang said. The direct production of pure formic acid solutions will help to promote commercial carbon dioxide conversion technologies.

An electrocatalysis reactor built at Rice University recycles carbon dioxide to produce pure liquid fuel solutions using electricity. The scientists behind the invention hope it will become an efficient and profitable way to reuse the greenhouse gas and keep it out of the atmosphere. Courtesy: Jeff Fitlow/Rice University[/caption]

The polymer-based solid electrolyte is coated with sulfonic acid ligands to conduct positive charge or amino functional groups to conduct negative ions. “Usually people reduce carbon dioxide in a traditional liquid electrolyte like salty water,” Wang said. “You want the electricity to be conducted, but pure water electrolyte is too resistant. You need to add salts like sodium chloride or potassium bicarbonate so that ions can move freely in water.

“But when you generate formic acid that way, it mixes with the salts,” he said. “For a majority of applications you have to remove the salts from the end product, which takes a lot of energy and cost. So we employed solid electrolytes that conduct protons and can be made of insoluble polymers or inorganic compounds, eliminating the need for salts.”

The rate at which water flows through the product chamber determines the concentration of the solution. Slow throughput with the current setup produces a solution that is nearly 30% formic acid by weight, while faster flows allow the concentration to be customized. The researchers expect to achieve higher concentrations from next-generation reactors that accept gas flow to bring out pure formic acid vapors.

The Rice lab worked with Brookhaven National Laboratory to view the process in progress. “X-ray absorption spectroscopy, a powerful technique available at the Inner Shell Spectroscopy (ISS) beamline at Brookhaven Lab’s National Synchrotron Light Source II, enables us to probe the electronic structure of electrocatalysts in operando — that is, during the actual chemical process,” said Eli Stavitski, lead beamline scientist at ISS. “In this work, we followed bismuth’s oxidation states at different potentials and were able to identify the catalyst’s active state during carbon dioxide reduction.”

With its current reactor, the lab generated formic acid continuously for 100 hours with negligible degradation of the reactor’s components, including the nanoscale catalysts. Wang suggested the reactor could be easily retooled to produce such higher-value products as acetic acid, ethanol or propanol fuels.

“The big picture is that carbon dioxide reduction is very important for its effect on global warming as well as for green chemical synthesis,” Wang said. “If the electricity comes from renewable sources like the sun or wind, we can create a loop that turns carbon dioxide into something important without emitting more of it.”

Rice University

– Edited by Chris Vavra, production editor, Control Engineering, CFE Media,

Original content can be found at Control Engineering.

Author Bio: Mike Williams is a senior media relations specialist in Rice University's Office of Public Affairs.